SYNTHESIS OF ALLOYS OF THE Sb2Se3-CuCr2Te4 SYSTEM AND PHYSICO-CHEMICAL PROPERTIES

  • E. Mamedov AzTU, Baku, Azerbaijan
  • I. Aliev Institute of Catalysis and Inorganic Chemistry named after M.F. Nagiyev National Academy of Sciences of Azerbaijan
  • L. Masieva AzTU, Baku, Azerbaijan
Keywords: alloy, quasi-binary, eutectic, microhardness, solid solution.

Abstract

The interaction in the quasi-ternary system Sb2Se3-CuTe-Cr2Te3 along the Sb2Se3-CuCr2Te4 section was studied by methods of physicochemical analysis: differential thermal (DTA), X-ray phase (XRD), microstructure (MSA), as well as by measuring the density and its microhardness and plotted. The phase diagram of the system is quasi-binary, eutectic type. The composition of the double eutectic formed in the system is 20 mol % CuCr2Te4 and a temperature of 490°C. As a result of the analysis of the microstructure, it was determined that there are single-phase fields based on the original components. It was found that at room temperature, solid solutions based on Sb2Se3 extend to 5 mol % CuCr2Te4, and on the basis of CuCr2Te4 solid solutions reach 13 mol % Sb2Se3.

Author Biographies

E. Mamedov , AzTU, Baku, Azerbaijan

Doctor of Chemical Sciences, prof. Head of the Department of Chemistry

I. Aliev , Institute of Catalysis and Inorganic Chemistry named after M.F. Nagiyev National Academy of Sciences of Azerbaijan

doctor of chemical sciences, prof., hands. lab.

L. Masieva , AzTU, Baku, Azerbaijan

graduate student

References

1. Kamruzzaman M., Chaoping Liu., Farid Ul Islam A.K.M., Zapien J.A. A comparative study on the electronic and optical properties of Sb2Se3 thin film // Fizika i tehnika poluprovodnikov. 2017. T. 51, vyp. 12. P. 1673-1678.
2. Zhou Y., Wang L., Chen S., Qin, S., Liu X., Chen J., Xue D.-J., Luo M., Cao Y., Cheng Y., Sargent E. H., and Tang J. Thin-film Sb2Se3 photovoltaics with oriented one-dimensional ribbons and benign grain boundaries. Nature Photonics. 2015. V. 9. № 6. P. 409–415. https://doi.org/10.1038/nphoton.2015.78
3. Praveen KumarT.S., Sathiaraj Thangaraj R. Optical properties of amorphous Sb2Se3:Sn films // J. Philosophical Magazine Letters. 2010. V. 90. Issue 3. P. 183-192 https://doi.org/10.1080/09500830903520704.
4. Maghraoyi-Mehezi H., Ben Nasr T., Dachraoui M. Synthesis, structure and optical properties of Sb2Se3. Materials Science in Semiconductor Processing 2013. V. 16. P. 179-184. https://doi.org/10.1016/j.mssp.2012.04.019
5. Chen C., Li W., Zhou Y., Chen C., Luo M., Liu X., Zeng K., Yang B., Zhang C., Han J., Tang J. Optical properties of amorphous and polycrystalline Sb2Se3 thin films prepared by thermal evaporation // Applied Physics Letters. 2015. V. 107. № 4. P. 043905.
6. Chen C., Bobela D.C., Yang Y. et al. Characterization of basic physical properties of Sb2Se3 and its relevance for photovoltaics // Front. Optoelectron. 2017. V. 10. P. 18–30. https://doi.org/10.1007/s12200-017-0702-z
7. Ju T., Koo B., Jo J. W., & Ko M. J. Enhanced photovoltaic performance of solution-processed Sb2Se3 thin film solar cells by optimizing device structure // Current Applied Physics, 2020. V. 20. № 2. P. 282-287. https://doi.org/10.1016/j.cap.2019.11.018
8. Magomedov A.Z., Aliev A.O., Aslanov M.A., Musaeva S.M., Dzhavadova S.D. Osobennost temperaturnoj zavisimosti spektralnogo raspredeleniya fotochuvstvitelnosti segnetoelektrikov-poluprovodnikov Sb2S3-Sb2Se3 // Vestnik Bakinskogo Universiteta, ser.fiz-mat. nauk, 2004. № 4. C.163-169.
9. Magomedov A.Z., Aliev A.O., Talybova D.A., Dzhahangirova S.A., Mamedov R.M., Aslanov M.A. Osobennosti Volt-Ampernoj harakteristiki segnetopoluprovodnikovyh kristallov sistemy Sb2S3-Sb2Se3.// Vestnik NANA. 2007. № 5. C. 87-93.
10. Magomedov A.Z., Gasanova L.G., Aliev A.O., Mamedov A.A., Aslanov M.A. Akusticheskie issledovaniya kristallov tverdyh rastvorov sistemy Sb2S3-Sb2Se3. //Fizika XIII. 2007. № 4. C.164-166.
11. Belov K.P., Tretyakov Yu.D., Gordeev I.V., Koroleva L.I., Pedko A.V., Bagorova S.D., Alferov V.A., Saksonov Yu.G., Shalimova M.A. Magnitnye svojstva halkogenidnyh shpinelej CdxCuxCr2S4, CdCr2Se4-y FeCr2S4-y // FTT. 1973. T.15. № 10. S. 3106-108.
12. Sever G.N. Anomalnyj fotomagnitoelektricheskij effekt v UDK 66.001.001.57:66.022:621.926/929 ferrimagnitnom poluprovodnike CdCr2Se4 // FTP. 1983. T. 17. №8.-S.1505-507.
13. Shumilkin N. S. Vzaimodejstvie v sistemah Su-In-Sg-Se(Te) v oblasti sushestvovaniya magnitnyh faz s vysokimi temperaturami magnitnogo uporyadocheniya (Ts). Dis. na soisk. kand. him. nauk. RAN IONH im. N.S.Kurnakova. 2002. 121 s.
14. Yamashita O., Yamauchi H., Yamaguchi Y. et.al. Magnetic Properties of the System CuCr2Se4.xYx (Y=C1, Br) // J. Phys. Soc. Jap. 1979. V. 47. № 2. P. 450-454.
15. Koroleva L.I., Lukina L.N., Busheva E.V., Shabunina GG., Aminov T.G Novye magnitnye poluprovodniki CuCr2Se4-xSbx // Izv. AN SSSR. Neorgan. materialy. 1999. T. 35. № 12. S.14251428.
16. Fiziko-himicheskie svojstva poluprovodnikovyh veshestv. Spravochnik. Moskva. Izd. Nauka.1979. 339 c.
17. Aliev I.I., Ismailova S.Sh., Shahbazov M.G. Issledovanie vzaimodejstviya v sisteme As2Te3-CuCr2Te4 // Zhurn. Evrazijskij Soyuz uchenyh. 2019. T. № 6(63). S.46-49.
18. Takeshi Suzuyama, Junji Awaka, Hiroki Yamamoto, Shuji Ebisua, Masakazu Ito, Takashi Suzuki, Takao Nakama, KatsumaYagasaki, Shoichi Nagata. Ferromagnetic-phase transition in the spineltype CuCr2Te4 // Journal of Solid State Chemistry. 2006. V. 179. № 1. P. 140-144. https://doi.org//10.1016/j.jssc.2005.10007
Published
2021-05-14
How to Cite
Mamedov , E., I. Aliev, and L. Masieva. 2021. “SYNTHESIS OF ALLOYS OF THE Sb2Se3-CuCr2Te4 SYSTEM AND PHYSICO-CHEMICAL PROPERTIES”. EurasianUnionScientists, May, 49-53. https://doi.org/10.31618/ESU.2413-9335.2021.4.85.1335.