CHARACTER OF INTERACTION AND GLASS FORMATION IN THE As2Se3-In2Se3 SYSTEM

  • I. Aliev Institute Catalysis and Inorganic Chemistry named after M.F. Nagiev National Academy of Sciences of Azerbaijan
  • D. Ajdarova Institute Catalysis and Inorganic Chemistry named after M.F. Nagiev National Academy of Sciences of Azerbaijan
  • T. Maksudova Institute Catalysis and Inorganic Chemistry named after M.F. Nagiev National Academy of Sciences of Azerbaijan
  • S. Mehdiyeva Institute Catalysis and Inorganic Chemistry named after M.F. Nagiev National Academy of Sciences of Azerbaijan
  • E. Kakhramanov Ganja State University
  • C. Ahmedova Adiyaman State University
  • M. Shahbazov Azerbaijani State Pedagogical University
DOI: https://doi.org/10.31618/ESU.2413-9335.2021.4.93.1573
Keywords: glass, crystal system, eutectic, microhardness, density.

Abstract

The kharacter of the interaction and glass formation in the As2Se3-In2Se3 system was investigated by the methods of physicochemical analysis (DTA, XRD, MSA, as well as by measuring the microhardness and determining the density) and the T-x phase diagram was constructed. The formation of a new compound of composition InAsSe3 in the As2Se3-In2Se3 system is established. The InAsSe3 compound is formed as a result of a peritactic reaction at 725оС. It was found that this InAsSe3 compound crystallizes in the tetragonal system with lattice parameters: a = 9.20 ± 0.02; c = 5.42 ± 0.02 Å, Z = 4, density ρpycn = 5.25.103 kg/m3, ρx-ray. = 5.86.103 kg/m3. In the As2Se3-In2Se3 system, solid solutions based on As2Se3 at room temperature reach 2 mol % In2Se3, and based on In2Se3-3 mol. % As2Sе3. It was found that in the As2Sе3-In2Se3 system upon slow cooling based on As2Se3, the glass formation region reaches 7 mol. % In2Se3, and in the mode of quenching in ice water up to 13 mol. % In2Se3.

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Published
2022-01-20
How to Cite
Aliev , I., D. Ajdarova, T. Maksudova, S. Mehdiyeva, E. Kakhramanov, C. Ahmedova, and M. Shahbazov. 2022. “CHARACTER OF INTERACTION AND GLASS FORMATION IN THE As2Se3-In2Se3 SYSTEM ”. EurasianUnionScientists, January, 39-44. https://doi.org/10.31618/ESU.2413-9335.2021.4.93.1573.
Issue
EURASIAN UNION OF SCIENTISTS. SERIES: MEDICAL, BIOLOGICAL AND CHEMICAL SCIENCES. VOLUME 1 №12(93) (2021)
Section
Article

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